Chris Jericho Week 1 (Singles Match): The Miz
Week 5 (SuperStars): Santino (talk to Santino at Royal Rumble to set this up)
Week 7 (Parking Lot): Cena
Week 8 (Diva Match): Maryse vs. Beth
Week 11 (Singles Match): Santino vs. Big Show (talk to Santino in the hall to setup your interference)
WrestleMania (Singles Match): Find Steamboat in the Green Room.
Christian Week 4: After the Peep Show, before talking to Tiffany, go to the top locker room on the map, and talk to Regal.
Week 5: Find Kane, and get challenged to an Inferno Match.
Week 7: Find CM Punk in the hallways, and talk to him.
Week 9: Find Jericho in the trainer's room.
Week 11: Find Legacy backstage. Fight them 2-on-1 at Superstars.
WrestleMania: Check the Green Room to challenge Stone Cold.
John Cena Week 4 (Backstage Brawl): Confront Sheamus in the middle locker room.
Week 5 (Tag Match on SD): Fight Truth & Consequences (talk to MVP to set this up).
Week 7 (Tag Match on SD): Truth & Consequences for the titles (unlocks civilian MVP).
Week 8 (Backstage Brawl): Legacy (unlocks civilian Cena and entrance).
Week 11 (Tag Team): Santino vs. Legacy
WrestleMania (Singles Match): Vince in the Green Room
Rey Mysterio Week 3 (Submission Match): Jericho
Week 4 (6 Man Tag): Los Conquistadors
Week 6 (Singles Match): R Truth
Week 9 (Singles Match): Bourne vs. Orton
Week 10 (Cage): Hurricane (talk to him in the lower locker room to set this up before teaming up with RVD)
WrestleMania (Extreme Rules): Terry Funk (find him in the Green Room)
Vs. Undertaker Week 2 (Backstage Brawl): Randy Orton
Week 3 (Backstage Brawl): Kozlov
Royal Rumble (Backstage Brawl): Ziggler
Week 9 (Tables Match): Big Show
Week 12 (Backstage Brawl): Batista
WrestleMania (Last Man Standing): The Rock